The earliest time for the morning berachos is after halachic midnight. The exception is “Asher nassan lasechvi binah…”, which can only be said after dawn.
Shabbos Bulletin Parshas Vayeira 5780 and Tefilla Halacha
About the Author: Lev Seltzer
Lev Seltzer has been a member of Beis Tefillah from just a short time after its founding. He currently manages the BTYA.org website, and can be found every morning in the BTYA "Vasikin Room" where he is the gabbai of the minyon.